Research reveals a bright future for a new lighting technology

A flexible, lightweight panel made by GE provides diffuse light. The
 panel is made of organic light-emitting diodes, or OLEDs. This kind of 
lighting could be more efficient and versatile than old-style light 
bulbs.
Flick on a light at home and chances are a glass bulb or tube will 
start to glow. The two most common types of electric lights — 
incandescent and fluorescent — have worked pretty well for a long time. 
Make that too long: Both types are so last century.
Incandescent bulbs waste most of their energy. Regular and compact 
fluorescent tubes are more efficient. However, they contain toxic 
mercury. Now lighting engineers want us to imagine electric lighting 
beyond the bulb.
Picture sheets of electric lights that can bend or twist. Your bedroom 
could have glowing sculptures instead of lamps. A living room window 
might be transparent by day, then light up at night. The whole kitchen 
ceiling might glow. And whole walls could be covered with programmable 
lighting. A few taps on a control panel might change its brightness, 
color or pattern.

PEEPO/ISTOCKPHOTO
It’s all possible with organic light-emitting diodes, or OLEDs. They 
are a new type of digital — or solid-state — lighting. Made from solid 
materials, they don’t require the vacuum now found in an incandescent 
bulb or the gas that’s encased within fluorescent tubes.
OLED technology doesn’t just promise new designs. It points to better 
efficiency, fewer environmental risks and longer-lasting products too.
Welcome to lighting in the digital age: The future is going to be bright.
Of sandwiches and coins
Right now, most indoor lighting depends on glass bulbs or tubes. A 
fluorescent lamp glows when electricity flows through a gas-filled tube.
 In old-style incandescent bulbs, electricity heats up a tungsten thread
 until it glows. These bulbs produce more heat than light. In fact, the 
filament can get much hotter than molten lava.
Digital or solid-state lighting is different. It doesn’t use 
electricity to make heat that produces light. Instead, it sends 
electricity through solid materials called semiconductors. Those 
materials can release energy directly as light through a process called 
electroluminescence (Ee-LEK-troh-LOOM-in-ESS-ents).
One form of digital lighting is already popular: light-emitting diodes,
 better known as LEDs. They light most flat-screen TVs and computer 
monitors. Traffic lights, car headlights and taillights, flashlights and
 even some flashy sneakers also use LEDs. While they’re used like bulbs,
 LEDs are actually bits of flat wafers. One 10 × 10 centimeter (4 × 4 
inch) wafer can yield thousands of chips as small as a grain of sand.
Both LEDs and OLEDs rely on electroluminescence. However, organic LEDs,
 or OLEDs, offer more design flexibility. Differences in the 
manufacturing process let OLEDs be made in bigger sheets on flexible 
surfaces. And while LEDs often function as bright point sources of 
light, OLEDs can provide softer, more diffuse light.
To understand an OLED, start by thinking of it as a sandwich.
Electrical conductors, called electrodes, make up the two outer layers 
of an OLED. One layer has extra electrons (the subatomic particles whose
 movement creates an electric current). The other layer has bonus 
“holes.” The holes are spaces where electrons can go. And at least one 
of the layers is transparent. That way, when an OLED lights up, people 
can see the illumination.

CANEK FUENTES-HERNANDEZ, GEORGIA INSTITUTE OF TECHNOLOGY
Wedged between the outer layers is a semiconductor. It carries electric
 current under some conditions but not others. In OLEDs, the 
semiconductor contains carbon. Carbon is found in all living things. 
Thus, scientists often say carbon-based materials are organic, even if 
they’re not alive. In OLEDs, the organic materials are usually polymers.
 (These are chemicals that have many repeating groups of atoms in long 
chains.)
Applying a power source to the OLED’s outer layers will make an 
electric current flow through the device. As that happens, the extra 
electrons from one outer layer enter the OLED’s semiconductor core.
When an electron finds a hole in the semiconductor, it drops into it. 
There it settles inside the organic layer, explains Yiting Zhu. She’s a 
researcher at the Lighting Research Center at Rensselaer Polytechnic 
Institute (RPI) in Troy, N.Y.
At this happens, the other outer layer pulls electrons out. That action
 puts new holes in the semiconductor. “One electrode injects electrons, 
and the other injects holes,” explains Valy Vardeny. He’s a physicist at
 the University of Utah in Salt Lake City. 
Free electrons have a higher energy level than do the electrons that 
orbit an atom’s nucleus. Think of how you’re all revved up when you’re 
playing sports. Electrons enter the semiconductor layer in that higher 
energy state.
When an electron settles into the semiconductor layer, it falls into a 
lower-energy hole. Think of how you might sink into a comfy armchair to 
rest after a big game. But now the extra energy has to go somewhere. The
 OLED releases that extra energy in the form of light. This is 
electroluminescence.
That’s not the end of the story. As long as the electric current flows,
 the outer layers keep injecting electrons and holes into the 
semiconductor. So the light stays on.
LIGHTING RESEARCH CENTER/RPI
Lighting with changeable colors
An OLED usually emits red, blue or green light. These are the three 
primary colors. Which color depends on what else the semiconductor layer
 contains besides carbon.
OLEDs in some high-end TVs, cell phones and tablets include layers that can produceall three primary colors.
The layered effect makes an OLED a bitlike a hero sandwich. Switching 
on and off these red, blue and green layers, either singly or in 
combination, allows an individual OLED to produce a full range of 
colors. To glow white, OLED lights usually combine the light emissions 
from all threelayers.For black, all layers would turn off.
Changing a semiconductor’s chemical make-up allows you to go beyond 
just color. It also can change a color’s hue and other characteristics. 
For instance, instead of just green, an OLED can be tuned to produce a 
vivid emerald green or a pale lime green. Still, whatever recipe is 
used, each semiconductor layer has been able to emit only one color at a
 time, notes Vardeny.
That’s because the semiconductor normally has just one of two 
electronic states. It’s like a coin with two sides. When it lands, it’s either heads or tails. In the semiconductor’s case, it can be one color or another. Never both.
LIGHTING RESEARCH CENTER/PI
Until now.
Recently, Vardeny and his colleagues coaxed a single semiconductor 
layer into emitting two different colorsof light— at the same time. They
 reported their discovery in the September 2013 issue of Scientific Reports.
“Finding a polymer that emits two colors is like finding a human being with two heads,” says Vardeny. “It’s that surprising.”
Quantum physics deals with what happens at the atomic or subatomic 
level. The new semiconductor contains a tiny bit of platinum. And at the
 level of quantum physics, that precious metal acts like a mixer. It 
essentially lets the semiconductor exhibit both electronic states — 
equivalent to the coin’s heads and tails — at once.  Thisallows the 
semiconductor to emit two different colorsat the same time.
Vardeny’s team made a semiconductor where one state emits violet light 
and the other emits yellow. Violet is really red plus blue light. Yellow
 is red plus green light. Those two hues include all three primary 
colors of light, so their combined light looks white.
The process offers a way to make white OLEDs with a single 
semiconductor. Using one layer instead of two or three could make OLED 
lighting less costly.

TEK BASEL, UNIVERSITY OF UTAH
Why organic?
Fluorescent lights can be unpleasant. Not OLEDs. “The lighting quality 
is better,” says Lu Li. He’s a materials engineer at the University of 
California, Los Angeles (UCLA). OLEDs have none of the flicker or glare 
associated with fluorescents, he notes. OLED light also is soft, or more
 diffused.
And OLEDs emit light in all directions. This quality makes OLEDs ideal 
for display screens as well as lighting, says Bernard Kippelen. He heads
 a center in Atlanta at the Georgia Institute of Technology where 
experts research OLEDs and other organic electronics. It’s called the 
Center for Organic Photonics and Electronics (COPE).
Look at a conventional TV or computer screen from the side. In many 
cases the image will appear distorted. But an OLED image will look 
clear, no matter what your viewing angle is. Backlights on conventional 
screens also make shadowy scenes seem too dark. OLED screens produce 
better contrast because each color layer itself lights up. And unlit 
black areas are all black from the absence of light — not backlit with 
dark gray.
Making regular LEDs requires very hot temperatures. Making OLEDs 
doesn’t. “They can be processed at nearly room temperature,” says 
Kippelen. As a result, OLEDs can be put on almost anything, from a sheet
 of glass to very thin plastic. Inkjet printers could even do the job.
Such features open up lots of design possibilities. “You can bend 
[OLEDs] into any shape you want,” says Nadarajah Narendran. He's the 
research director at RPI's Lighting Research Center. Imagine having a 
roll-up TV or a cell phone that wraps around your wrist. A ceiling could
 have curved lighting. “Even your drapes can become OLEDs,” he says.
These ideas are not just dreams. Li and other UCLA researchers have 
already made a flexible OLED. They described it in the September 2013 Nature Photonics. (Photonics deals with the properties and transmission of tiny particles of light energy.)
Their new OLED material is bendable and stretchable. Plus, you can see through it.
“It almost looks like a gummy bear, but its stretchability is better,” 
notes Li. Think about the elastic hair bands that hold ponytails in 
place. The new OLED material is about as stretchable, he says. 

JIAJIE LIANG, LU LI, XIAOFAN NIU, ZHIBIN YU AND QUIBING PEI
OLEDs also are environmentally friendly. Regular LEDs can contain 
arsenic. And fluorescent lights usually have mercury in them. Both are 
toxic. Disposing of them requires special handling. That’s not true for 
OLEDs. “You throw them away, and in a few days they are part of Mother 
Earth,” says the University of Utah’s Vardeny.
And, Zhu adds, “Energy savings are going to be huge.” Within five or 
six years, OLEDs could provide twice as much light per unit of power as 
fluorescent bulbs. Even more dramatically, the output per watt could be 
10 or 20 times as high as that of traditional bulbs.
Moving ahead
The way OLEDs emit light is only part of the story. The way people 
perceive and experience light matters too. Thus, Narendran’s group at 
RPI studies what types of lighting would and wouldn’t work in the real 
world. Just because something is possible with OLEDs doesn’t mean it’s a
 good idea, says Narendran.
“If every inch of your wall and ceiling is glowing, it will drive you 
nuts,” he predicts. Most people prefer some variation and shadows. These
 qualities add visual interest. They also make it easier to see the 
texture of furniture or fabrics.
Efficiency and durability matter too. To increase both, RPI’s Zhu tests
 OLED technologies. Some of the goals include making OLEDs cheaper to 
manufacture and to use. They also need to be more rugged and last 
longer. Fortunately, experts are making progress on all these fronts, 
she says.
Meanwhile, Kippelen’s team has found a way to make the outer electrode 
layers more stable. Over time, the common metals in many electrodes 
react with oxygen in the presence of moisture. In other words, they 
rust. New organic materials can reduce that problem. The researchers 
described the materials two years ago in the journal Science.
These and other improvements will help OLEDs compete better with 
existing technologies. OLED displays are already in some smartphones and
 tablets. The prices for larger displays remain high. For example, today
 a top-of-the-line 55-inch OLED TV may cost $9,000.
Lighting rooms with OLEDs is even newer. A few offices already 
incorporate the pioneering technology. Among them: the U.S. embassy in 
Helsinki, Finland.

COURTESY ACUITY BRANDS
For now, LED technology is more advanced than that for OLEDs. Nor will 
OLED lights ever entirely replace LEDs. Narendran says LEDs will always 
work better for smaller light sources that direct light to a certain 
spot. “OLEDs are good for larger areas and more diffuse light within the
 space,” he says. 
For the typical home, office or school, OLEDs still aren’t big enough, 
affordable enough or durable enough. Getting there will take several 
more years of work by researchers. When OLED lighting does enter wider 
use, it will offer lots of possibilities beyond the traditional light 
bulb.
“OLEDs have the potential to change the whole environment,” Narendran 
predicts. For example, OLED lighting needn’t be limited to fixtures. It 
could become part of the building. It could be part of the furniture. It
 might even become part of our clothes.

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