Research reveals a bright future for a new lighting technology
Flick on a light at home and chances are a glass bulb or tube will
start to glow. The two most common types of electric lights —
incandescent and fluorescent — have worked pretty well for a long time.
Make that too long: Both types are so last century.
Incandescent bulbs waste most of their energy. Regular and compact
fluorescent tubes are more efficient. However, they contain toxic
mercury. Now lighting engineers want us to imagine electric lighting
beyond the bulb.
Picture sheets of electric lights that can bend or twist. Your bedroom
could have glowing sculptures instead of lamps. A living room window
might be transparent by day, then light up at night. The whole kitchen
ceiling might glow. And whole walls could be covered with programmable
lighting. A few taps on a control panel might change its brightness,
color or pattern.
It’s all possible with organic light-emitting diodes, or OLEDs. They
are a new type of digital — or solid-state — lighting. Made from solid
materials, they don’t require the vacuum now found in an incandescent
bulb or the gas that’s encased within fluorescent tubes.
OLED technology doesn’t just promise new designs. It points to better
efficiency, fewer environmental risks and longer-lasting products too.
Welcome to lighting in the digital age: The future is going to be bright.
Of sandwiches and coins
Right now, most indoor lighting depends on glass bulbs or tubes. A
fluorescent lamp glows when electricity flows through a gas-filled tube.
In old-style incandescent bulbs, electricity heats up a tungsten thread
until it glows. These bulbs produce more heat than light. In fact, the
filament can get much hotter than molten lava.
Digital or solid-state lighting is different. It doesn’t use
electricity to make heat that produces light. Instead, it sends
electricity through solid materials called semiconductors. Those
materials can release energy directly as light through a process called
electroluminescence (Ee-LEK-troh-LOOM-in-ESS-ents).
One form of digital lighting is already popular: light-emitting diodes,
better known as LEDs. They light most flat-screen TVs and computer
monitors. Traffic lights, car headlights and taillights, flashlights and
even some flashy sneakers also use LEDs. While they’re used like bulbs,
LEDs are actually bits of flat wafers. One 10 × 10 centimeter (4 × 4
inch) wafer can yield thousands of chips as small as a grain of sand.
Both LEDs and OLEDs rely on electroluminescence. However, organic LEDs,
or OLEDs, offer more design flexibility. Differences in the
manufacturing process let OLEDs be made in bigger sheets on flexible
surfaces. And while LEDs often function as bright point sources of
light, OLEDs can provide softer, more diffuse light.
To understand an OLED, start by thinking of it as a sandwich.
Electrical conductors, called electrodes, make up the two outer layers
of an OLED. One layer has extra electrons (the subatomic particles whose
movement creates an electric current). The other layer has bonus
“holes.” The holes are spaces where electrons can go. And at least one
of the layers is transparent. That way, when an OLED lights up, people
can see the illumination.
Wedged between the outer layers is a semiconductor. It carries electric
current under some conditions but not others. In OLEDs, the
semiconductor contains carbon. Carbon is found in all living things.
Thus, scientists often say carbon-based materials are organic, even if
they’re not alive. In OLEDs, the organic materials are usually polymers.
(These are chemicals that have many repeating groups of atoms in long
chains.)
Applying a power source to the OLED’s outer layers will make an
electric current flow through the device. As that happens, the extra
electrons from one outer layer enter the OLED’s semiconductor core.
When an electron finds a hole in the semiconductor, it drops into it.
There it settles inside the organic layer, explains Yiting Zhu. She’s a
researcher at the Lighting Research Center at Rensselaer Polytechnic
Institute (RPI) in Troy, N.Y.
At this happens, the other outer layer pulls electrons out. That action
puts new holes in the semiconductor. “One electrode injects electrons,
and the other injects holes,” explains Valy Vardeny. He’s a physicist at
the University of Utah in Salt Lake City.
Free electrons have a higher energy level than do the electrons that
orbit an atom’s nucleus. Think of how you’re all revved up when you’re
playing sports. Electrons enter the semiconductor layer in that higher
energy state.
When an electron settles into the semiconductor layer, it falls into a
lower-energy hole. Think of how you might sink into a comfy armchair to
rest after a big game. But now the extra energy has to go somewhere. The
OLED releases that extra energy in the form of light. This is
electroluminescence.
That’s not the end of the story. As long as the electric current flows,
the outer layers keep injecting electrons and holes into the
semiconductor. So the light stays on.
Lighting with changeable colors
An OLED usually emits red, blue or green light. These are the three
primary colors. Which color depends on what else the semiconductor layer
contains besides carbon.
OLEDs in some high-end TVs, cell phones and tablets include layers that can produceall three primary colors.
The layered effect makes an OLED a bitlike a hero sandwich. Switching
on and off these red, blue and green layers, either singly or in
combination, allows an individual OLED to produce a full range of
colors. To glow white, OLED lights usually combine the light emissions
from all threelayers.For black, all layers would turn off.
Changing a semiconductor’s chemical make-up allows you to go beyond
just color. It also can change a color’s hue and other characteristics.
For instance, instead of just green, an OLED can be tuned to produce a
vivid emerald green or a pale lime green. Still, whatever recipe is
used, each semiconductor layer has been able to emit only one color at a
time, notes Vardeny.
That’s because the semiconductor normally has just one of two
electronic states. It’s like a coin with two sides. When it lands, it’s either heads or tails. In the semiconductor’s case, it can be one color or another. Never both.
Until now.
Recently, Vardeny and his colleagues coaxed a single semiconductor
layer into emitting two different colorsof light— at the same time. They
reported their discovery in the September 2013 issue of Scientific Reports.
“Finding a polymer that emits two colors is like finding a human being with two heads,” says Vardeny. “It’s that surprising.”
Quantum physics deals with what happens at the atomic or subatomic
level. The new semiconductor contains a tiny bit of platinum. And at the
level of quantum physics, that precious metal acts like a mixer. It
essentially lets the semiconductor exhibit both electronic states —
equivalent to the coin’s heads and tails — at once. Thisallows the
semiconductor to emit two different colorsat the same time.
Vardeny’s team made a semiconductor where one state emits violet light
and the other emits yellow. Violet is really red plus blue light. Yellow
is red plus green light. Those two hues include all three primary
colors of light, so their combined light looks white.
The process offers a way to make white OLEDs with a single
semiconductor. Using one layer instead of two or three could make OLED
lighting less costly.
Why organic?
Fluorescent lights can be unpleasant. Not OLEDs. “The lighting quality
is better,” says Lu Li. He’s a materials engineer at the University of
California, Los Angeles (UCLA). OLEDs have none of the flicker or glare
associated with fluorescents, he notes. OLED light also is soft, or more
diffused.
And OLEDs emit light in all directions. This quality makes OLEDs ideal
for display screens as well as lighting, says Bernard Kippelen. He heads
a center in Atlanta at the Georgia Institute of Technology where
experts research OLEDs and other organic electronics. It’s called the
Center for Organic Photonics and Electronics (COPE).
Look at a conventional TV or computer screen from the side. In many
cases the image will appear distorted. But an OLED image will look
clear, no matter what your viewing angle is. Backlights on conventional
screens also make shadowy scenes seem too dark. OLED screens produce
better contrast because each color layer itself lights up. And unlit
black areas are all black from the absence of light — not backlit with
dark gray.
Making regular LEDs requires very hot temperatures. Making OLEDs
doesn’t. “They can be processed at nearly room temperature,” says
Kippelen. As a result, OLEDs can be put on almost anything, from a sheet
of glass to very thin plastic. Inkjet printers could even do the job.
Such features open up lots of design possibilities. “You can bend
[OLEDs] into any shape you want,” says Nadarajah Narendran. He's the
research director at RPI's Lighting Research Center. Imagine having a
roll-up TV or a cell phone that wraps around your wrist. A ceiling could
have curved lighting. “Even your drapes can become OLEDs,” he says.
These ideas are not just dreams. Li and other UCLA researchers have
already made a flexible OLED. They described it in the September 2013 Nature Photonics. (Photonics deals with the properties and transmission of tiny particles of light energy.)
Their new OLED material is bendable and stretchable. Plus, you can see through it.
“It almost looks like a gummy bear, but its stretchability is better,”
notes Li. Think about the elastic hair bands that hold ponytails in
place. The new OLED material is about as stretchable, he says.
OLEDs also are environmentally friendly. Regular LEDs can contain
arsenic. And fluorescent lights usually have mercury in them. Both are
toxic. Disposing of them requires special handling. That’s not true for
OLEDs. “You throw them away, and in a few days they are part of Mother
Earth,” says the University of Utah’s Vardeny.
And, Zhu adds, “Energy savings are going to be huge.” Within five or
six years, OLEDs could provide twice as much light per unit of power as
fluorescent bulbs. Even more dramatically, the output per watt could be
10 or 20 times as high as that of traditional bulbs.
Moving ahead
The way OLEDs emit light is only part of the story. The way people
perceive and experience light matters too. Thus, Narendran’s group at
RPI studies what types of lighting would and wouldn’t work in the real
world. Just because something is possible with OLEDs doesn’t mean it’s a
good idea, says Narendran.
“If every inch of your wall and ceiling is glowing, it will drive you
nuts,” he predicts. Most people prefer some variation and shadows. These
qualities add visual interest. They also make it easier to see the
texture of furniture or fabrics.
Efficiency and durability matter too. To increase both, RPI’s Zhu tests
OLED technologies. Some of the goals include making OLEDs cheaper to
manufacture and to use. They also need to be more rugged and last
longer. Fortunately, experts are making progress on all these fronts,
she says.
Meanwhile, Kippelen’s team has found a way to make the outer electrode
layers more stable. Over time, the common metals in many electrodes
react with oxygen in the presence of moisture. In other words, they
rust. New organic materials can reduce that problem. The researchers
described the materials two years ago in the journal Science.
These and other improvements will help OLEDs compete better with
existing technologies. OLED displays are already in some smartphones and
tablets. The prices for larger displays remain high. For example, today
a top-of-the-line 55-inch OLED TV may cost $9,000.
Lighting rooms with OLEDs is even newer. A few offices already
incorporate the pioneering technology. Among them: the U.S. embassy in
Helsinki, Finland.
For now, LED technology is more advanced than that for OLEDs. Nor will
OLED lights ever entirely replace LEDs. Narendran says LEDs will always
work better for smaller light sources that direct light to a certain
spot. “OLEDs are good for larger areas and more diffuse light within the
space,” he says.
For the typical home, office or school, OLEDs still aren’t big enough,
affordable enough or durable enough. Getting there will take several
more years of work by researchers. When OLED lighting does enter wider
use, it will offer lots of possibilities beyond the traditional light
bulb.
“OLEDs have the potential to change the whole environment,” Narendran
predicts. For example, OLED lighting needn’t be limited to fixtures. It
could become part of the building. It could be part of the furniture. It
might even become part of our clothes.
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